This standard is formulated pursuant to rules provided in the GB/T 1.1 -2009.
This standard replaces the National Food Safety Standard Maximum Residue Limits for Pesticides in Food (GB 2763-2016) and the National Food Safety Standard Maximum Residue Limits for 43 Pesticides in Food (GB 2763.1-2018), and main technical changes are as follows compared with GB 2763-2016 and GB 2763.1-2018:
- Revised the definition of 6 pesticide residues including 2,4-di-isooctyl and the daily allowable intake of 21 pesticides such as Abamectin in the original standard.
- Added 51 kinds of pesticides including 2,4-drip dimethylamine salt, and deleted 1 kind of haloxyfop, and its maximum residue limit is combined into flupiroxicam and haloxyfop-P-methyl;
- Revised the Chinese and English common names of 5 pesticides including metriam.
- Added 2967 maximum pesticide residue limits;
- Revised 28 maximum pesticide residue limits.
- The partial limit values of 12 pesticides including glufosinate-ammonium were changed from temporary limit to formal limit.
- The partial limit values of 17 pesticides such as dithianon were changed from the formal limit to the temporary limit.
- Added 45 testing method standards, removed 17 testing method standards, and revised 9 testing method standards.
- Revised normative annex A, added 22 food names such as lupin, revised 7 food names and revised 2 food classifications;
- Revised normative annex B and added 11 pesticides.
The previous releases of the standards replaced by this standard are as follows:
GB 2763-2005, GB 2763-2012, GB 2763-2014, GB 2763-2016.
GB 2763.1-2018.
1 Scope
National Food Safety Standard Maximum Residue Limits of Pesticides in Foods
This standard sets the 7,107 maximum residue limits of 483 pesticides including 2,4-D, etc. in foods. The standard applies to foods related to residue limits.
The food categories and testing parts (Appendix A) are used to define the application scope of the pesticide’s maximum residue limits, which applies only to this standard. For instance, the maximum residue limit of a pesticide is applicable for a certain food category, all the food in this category will be applicable to this MRL, unless otherwise specified.
The List of Pesticides that are Exempted from Developing MRL Standards in Foods (the Normative Reference Annex B) is used to define the scope of pesticides that do not need MRLs developed in foods.
2 Normative reference
The following documents are essential for the application of this document. For dated references, only the dated versions apply to this standard. For not dated references, the latest versions (including all modifications) apply to this standard.
The supporting testing method that meets the testing requirements is selected for testing. After the release of this standard, the newly released and implemented national food safety standard (GB 23200) is also applicable to the testing of corresponding parameters.
GB/T 5009.19 Determination of organochlorine pesticide multiresidues in foods GB/T 5009.20 Determination of organophosphorous pesticide residues in foods GB/T 5009.21 Determination of carbaryl residues in cereals, oils and vegetables GB/T 5009.36 Analytical methods for hygienic standard of grain
GB/T 5009.102 Determination of phoxim pesticide residues in vegetable foods
GB/T 5009.103 Determination of methamidophos and acephate pesticide residues in vegetable foods GB/T 5009.104 Determination of carbamate pesticide residues in vegetable foods
GB/T 5009.105 Determination of chlorothalonil residues in cucumber GB/T 5009.107 Determination of diazinon residues in vegetable foods
GB/T 5009.110 Determination of cypermethrin,fenvalerate and deltamethrin residues in vegetable foods GB/T 5009.113 Determination of thiocyclam residues in rice
GB/T 5009.114 Determination of bisultap residues in rice GB/T 5009.115 Determination of tricyclazole residues in rice
GB/T 5009.126 Determination of triadmefon residues in vegetable foods GB/T 5009.129 Determination of ethoxyquin residues in fruits
GB/T 5009.130Determination of fomesafen residues in soybeans and cereals GB/T 5009.131 Determination of phosmet residues in vegetable foods
GB/T 5009.132Determination of atrazine residues in foods
GB/T 5009.133 Determination of chlorotoluron residues in grains GB/T 5009.134 Determination of molinate residues in rice
GB/T 5009.135 Determination of chlorbenzuron residues in vegetable foods GB/T 5009.136Determination of quintozene residues in vegetable foods
GB/T 5009.142 Determination of fluazifop-butyl and its acid residues in vegetable food GB/T 5009.143 Determination of amitraz residues in vegetables,fruits,edible oil
GB/T 5009.144 Determination of isofenphos-methyl residues in vegetable foods
GB/T 5009.145 Determination of organophosphorus and carbamate pesticide multiresidues in vegetable foods GB/T 5009.146 Determination of organochlorines and pyrethroid pesticide multiresidues in vegetable foods GB/T 5009.147 Determination of diflubenzuron residues in vegetable foods
GB/T 5009.155 Determination of isoprothiolane residues in rice GB/T 5009.160 Determination of semianitraz residues in fruits
GB/T 5009.161 Determination of organophosphorus pesticide multiresidues in animal foods
GB/T 5009.162 Determination of organochlorine pesticide and pyrethroid pesticide multiresidues in animal original foods
GB/T 5009.164 Determination of butachlor residues in rice
GB/T 5009.165 Determination of 2, 4-D butylate residues in grains
GB/T 5009.172 Determination of trifluralin residues in soybean, peanut, soybean oil, peanut oil. GB/T 5009.174 Determination of metolachlor residues in peanut and soybean
GB/T 5009.175 Determination of 2, 4-D in grains and vegetables
GB/T 5009.176 Determination of dicofol residues in tea, fruits, edible evgetable oils GB/T 5009.177 Determination of propanil residues in rice
GB/T 5009.180 Determination of oxadiazon residues in cereals and peanuts GB/T 5009.184 Determination of buprofezin in cereals and vegetables GB/T 5009.200 Determination of difenzoquat residues in wheat
GB/T 5009.201 Determination of diniconazole residues in pear
GB/T 5009.218 Determination of multi pesticide residues in fruits and vegetables GB/T 5009.219 Determination of the residues of chlorcholine chloride in cereals GB/T 5009.22 0Determination of the residues of anilazine in cereals
GB/T 5009.221 Determination of the residues of diquat in cereals
GB/T 14553 Cereal, Fruit and Vegetable Quality - Determination of Organophosphorus pesticides -Gas chromatography GB/T 14929.2 Method for Determination of Aldicarb Residues in Peanut, Cottonseed Oil and Peanut Oil
GB/T 19650 Method for determination of 478 pesticides and related chemicals residues in animal muscles-GC-MS method GB/T 20769 Determination of 450 pesticides and related chemicals residues in fruits and vegetables-LC-MS-MS method GB/T 20770 Method for determination of 486 pesticides and related chemicals residues in grains-LC-MS-MS method
GB/T 20771 D etermination of 486 pesticides and related chemicals residues in honey - LC-MS-MS method
GB/T 20772 Determination of 461 pesticides and related chemicals residues in animal muscles-LC-MS-MS method GB/T 22243Determination of residue limits of fluroxypyr in rice,vegetable and fruit
GB/T 22979Determination of boscalid residues in milk and milk powder-GC-MS method
GB 23200.2 National Food Safety Standard Testing Methods for Residue of Herbicides Part 2: Determination of Diphenyl Ether Herbicides Residues in Cereal and Oilseed by GC/MS Method
GB 23200.3National Food Safety Standard-Determination of cyclohexanediones herbicide residues in foods Liquid chromatography-mass spectrometry
GB 23200.6National Food Safety Standard Determination of amitrole residue in foods Liquid chromatography-mass spectrometry
GB 23200.8 National Food Safety Standard Determination of Residues of 500 Herbicides and Relevant Chemicals in Fruits and Vegetables by GC/MS Method
GB 23200.9National Food Safety Standard Determination of Residues of 475 Pesticides and Relevant Chemicals in Cereal by GC/MS Method
GB 23200.11National Food Safety Standard Determination of 413 pesticides and related chemicals residues in mulberry twig, honeysuckle, barbary wolfberry fruitand lotus leaf Liqulid chromatography-mass spectrometry
GB 23200.13 National Food Safety Standard Determination of Residues of 448 Pesticides and Relevant Chemicals in Tea Liquid Chromatography-Mass Spectrography
GB 23200.14National Food Safety Standard Determination of Residues of 512 Pesticides and Relevant Chemicals in Fruit/Vegetable Juice and Fruit Wine Liquid Chromatography-Mass Spectrography
GB23200.15 National Food Safety Standard Determination of Residues of 503 Pesticides and Relevant Chemicals in Edible Fungi Gas Chromatography-Mass Spectrography
GB23200.16 National Food Safety Standard Determination of Ethephon Residue in Fruits and Vegetables Gas chromatography
GB23200.19 National Food Safety Standard Determination of Abamectin in Fruits and Vegetables Liquid Chromatography GB23200.20 National Food Safety Standard Determination of Abamectin Residue in Foods Liquid Chromatography-Mass
Spectrography/ Mass Spectrography
GB23200.22 National Food Safety Standard Determination of maleic hydrazide residue in nuts and nut products
GB23200.24 National Food Safety Standard Determination of Eleven Herbicides Residues in Grains and Soybean Gas Chromatography-Mass Spectrography
GB23200.29 National Food Safety Standard Determination of Fenpyroximate Residue in Fruits and Vegetables Liquid Chromatography
GB23200.31 National Food Safety Standard Determination of flumioxazin Residue in Foods Gas Chromatography-Mass Spectrography
GB23200.32 National Food Safety Standard Determination of Daminozide Residue in Foods Gas Chromatography-Mass Spectrography
GB23200.33 National Food Safety Standard–Determination of Benoxacor, Anilofos,Allidochlor 110 pesticides residues in foods Gas chromatography-mass spectrometry
GB23200.34 National Food Safety Standard Determination of 65 Pesticides in Foods (including Aldoxycarb, Pyraclostrobine and Azoxystrobin) Liquid Chromatography–Mass Spectrometry / Mass Spectrometry
GB23200.37 National Food Safety Standard Determination of 20 Pesticides Residues in Foods (including Nitenpyram, Dinotefuran) Liquid Chromatography–Mass Spectrometry / Mass Spectrometry
GB23200.38 National Food Safety Standard-Determination of cyclohexanedione herbicides residue in plant-derived foods Liquid chromatography-mass spectrometry
GB23200.39 National Food Safety Standard-Determination of thiamethoxam and its metabolite clothianidin residues in foods Liquid chromatography-mass spectrometry
GB23200.43 National Food Safety Standard Determination of Quinclorac Residue in Grains and Oil Seeds Gas chromatography
GB23200.45 National Food Safety Standard-Determination of diflubenzuron residue in foods-Liquid chromatography-mass spectrometry
GB23200.46 National Food Safety Standard-Determination of Pyrimethanil, Mepanipyrim, Myclobutanil, Azoxystrobin Resides in Foods Gas Chromatography-Mass Spectrography
GB23200.47 National Food Safety Standard Determination of Clofentezine Residue in Foods Gas Chromatography-Mass Spectrography
GB23200.49 National Food Safety Standard Determination of Difenoconazole Residue in Foods Gas Chromatography-Mass Spectrography
GB23200.50 National Food Safety Standard Determination of pyridine pesticides residue in foods Liquid chromatography - mass spectrometry
GB23200.51 National Food Safety Standard Determination of Dinotefuran Residue in Foods Liquid Chromatography–Mass Spectrometry / Mass Spectrometry
GB23200.53 National Food Safety Standard Determination of flusilazole Residue in Foods Gas Chromatography-Mass Spectrography
GB23200.54 National Food Safety Standard Determination of Strobilurin Fungicide Residues in Foods Gas Chromatography-Mass Spectrography
GB23200.56 National Food Safety Standard-Determination of quinoxyfen residue in foods GB23200.57 National Food Safety Standard Determination of acetochlor Residue in Foods GB23200.60 National Food Safety Standard Determination of Clodinafop-propargyl Residue in Foods
GB23200.62 National Food Safety Standard–Determination of flumiclorac-pentyl residue in foods-Gas chromatography- mass spectrometry
GB23200.64 National Food Safety Standard-Determination of pyriproxyfen residue in foods-Liquid chromatography-mass spectromtry
GB23200.65 National Food Safety Standard Determination of tetraconazole residues in food
GB23200.68 National Food Safety Standard–determination of boscalid residue in foods Gas chromatography-mass spectrometry
GB23200.69 National Food Safety Standard Determination of dinitroaniline Pesticide Residue in Foods Liquid Chromatography–Mass Spectrometry / Mass Spectrometry
GB23200.70 National Food Safety Standard Determination of Acifluorfen Residue in Foods Liquid Chromatography–Mass Spectrometry / Mass Spectrometry
GB23200.72 National Food Safety Standard-Determination of phenylbenzamide pesticides residues in foods Gas chromatography-mass spectrometry
GB23200.73 National Food Safety Standard-Determination of rotenone and azadirachtin residues in foods-Liquid Chromatography-mass spectrometry
GB23200.74 National Food Safety Standard Determination of Jiangangmycin Residue in Foods Liquid Chromatography– Mass Spectrometry / Mass Spectrometry
GB23200.75 National Food Safety Standard–Determination of flonicamid residue in foods
GB23200.76 National Food Safety Standard-Determination of flubendiamide residue in foods Liquid chromatography-mass spectrometry
GB23200.83 National Food Safety Standard Testing Methods of Iprobenfos Residue in Foods
GB23200.104 National Food Safety Standard–Determination of MCPA and MCPB residues in meat and meat products Liquid chromatography-mass spectrometry
GB23200.108 National Food Safety Standard-Determination of glufosinate-ammonium residue in foods of plant origin- Liquid chromatography tandem mass spectrometry
GB23200.109 National Food Safety Standard-Determination of clopyralid in foods of plant origin- Liquid chromatography- mass spectrometry
GB23200.110 National Food Safety Standard-Determination of forchlorfenuron in foods of plant origin-Liquid chromatography tandem mass spectrometry
GB23200.111 National Food Safety Standard-Determination of flumetsulamin foods of plant origin-Liquid chromatography tandem mass spectrometry
GB23200.112 National Food Safety Standard–Determination of 9 carbamate pesticides and metabolites residues in foods of plant origin-Liquid chromatography-post-column derivation method
GB23200.113 National Food Safety Standard Determination of 208 pesticides and metabolites residues in foods of plant origin- Gas chromatography-tandem mass spectrometry method
GB23200.115 National Food Safety StandardDetermination of fipronil and metabolites residues in eggs Liqiud chromatography-tandem mass spectrometry method
GB/T23204 Determination of 519 pesticides and related chemicals residues in tea. GC-MS method GB/T23210 rmination of 511 pesticides and related chemicals residues in milk and milk powder -GC-MS
GB/T23211 Determination of 493 pesticides and related chemicals residues in milk and milk powder –LC-MS-MS method GB/T23376 Determination of pesticides residues in tea - GC/MS method
GB/T23379 Determination of imidacloprid residues in fruits,vegetables and teas - HPLCHPLC
GB/T23584 Determination of acetamiprid residue in fruits and vegetables – Liquid chromatography-tandem mass spectrometry
GB/T23750 Determination of Glyphosate residues in plant products-GC-MS method GB/T23816 Method for determination of triazine herbicide residues in soybean GB/T23818 Determination of imidazolinone herbicide residues in soybean
GB/T25222 Inspection of grain and oils - Determination of phosphide residues in grain - Spectrophotometric method GB29707 National Food Safety StandardDetermination of marker residues of Amitraz in milk by Gas Chromatographic
method
NY/T 761 Pesticide multi-residue screen methods for determination of organophosphorus pesticides, organochlorine pesticides, pyrethroid pesticides and carbamate pesticides in vegetables and fruits
NY/T1096 Determination of Glyphosate Residues in food
NY/T1277 Determination of Iprodione Residues in Vegetables by HPLC
NY/T1379 Multi-residue Determination of 334 Pesticides in Vegetable by GC/MS and LC/MS NY/T1434 Multi-residue Determination of 2 4 - D and Other 12 Herbicides in Vegetable by LC/MS NY/T1453 Determination of 16 pesticide residues in fruits and vegetables by LC - MS/MS NY/T1455 Determination of myclobutanil residue in fruits by gas chromatogram
NY/T1456 Determination of prochloraz residue in fruits by gas chromatography
NY/T1616 Determination of Nine sulfonylurea herbicides residues in soils by LC-MS NY/T1652 Determination of propargite residues in vegetables and fruits - GC
NY/T1679 Determination of carbamate pesticide residues in vegetable foods by LC - MS/MS
NY/T1680 Determination of Carbendazim and other Three Benzimidazoles in vegetable and fruit by HPLC NY/T1720 Determination of seven benzoylurea pesticides residues in fruits and vegetables by HPLC NY/T1722 Determination of anilazine residue in vegetables by HPLC
NY/T1725 Determination of cyromazine residue in vegetables by HPLC
NY/T2820 Determination of yishijing tebufenozide, methoxyfenozide, furan tebufeno zide and chromafenozide residues in plant foods-LC-MS-MS method
SN/T0134 Determination of pesticide residues of 12 kinds carbamates including oxamyl in foods for import and export –LC- MS/MS method
SN/T0139 Method for determination of dithiocarbamate residues in grain for export SN/T0157 Method for determination of dithiocarbamateresidue in fruit for export
SN/T0162 Method for the determination of thiophanate-methyl, thiophanate, carbendazim, benomyl and thiabendazole residues in foods for exports - HPLCHPLC
SN/T0192 Method for determination of bromopropylate residues in fruits for export
SN/T0217 Determination of Residual Amounts of Various Chrysanthemum Esters in Plant-derived Foods for Export-Gas Chromatography-Mass Spectrometry
SN/T0293 Determination of Paraquat and diquat Residues in Plant-derived Foods for Export-Liquid Chromatography-Mass Spectrometry/Mass Spectrometry
SN/T0519 Determination of propiconazole residue in food for import and export SN/T0525 Determination of phenylbutatin residues in cereals and oilseeds for export
SN/T0592 Method for the determination of fenbutatin oxide residues in cereals and oil seeds for export SN0654 Method for the determination of captan residues in fruits for export
SN/T0685 Method for the determination of propamocarb residues inf cereals for export SN/T0695 Method for the determination of triforine residues in cereals for export SN/T0697 Determination of oxamyl residues in export meat and meat products SN/T0701 Method for the determination of phosphamidon residues in cereals for export
SN/T0931 Method for the determination of prohexadione-calcium residue in cereals for exports - Liquid chromatography SN/T 1477 Inspection of paclobutrazol residues in food for import and export
SN/T 1541 Inspection of the total residues of dithiocarbamate pesticides in tea for export
SN/T 1605 Inspection of cyanazin fluometuron atrazine propanil and linuron residues in products of plant origin for import and export - HPLC
SN/T 1606 Inspection of phenoxy acid herbicides residues in products of plant origin for import and export - gc
SN/T 1739 Determination of organophosphrous pesticides residues in cereals and oil seeds for import and export-Gas chromatography mass spectrometry method
SN/T 1923 Determination of glyphosate residues in food for import and export - HPLC-MS/MS method SN/T 1968 Determination of prometryne residues in food for import and export.GC-MS Method
SN/T 1969 Determination of bifenthrin residue in food for import and export-GC-MS method
SN/T 1976 Determination of azoxystrobin residues in fruit and vegetable for import and export-GC method SN/T 1982 Determination of fipronil residues in food for import and export-GC-MS method
SN/T 1986 Determination of chlorfenapyr residues in food for import and export
SN/T 2095 Determination of chlorfluazuron residues in vegetables for import and export - HPLC SN/T 2147 Determination of cadusafos residues in food for import and export
SN/T 2151 Determination of pesticides residue of 28 kinds of including bioresmethrin, acinathrin, bifenthrin in food import and export - GC-MS method
SN/T 2152 Determination of hexaflumuron residue in food for import and export - HPLC-MS/MS method SN/T 2158 Determination of chlorpyrifos residue in foods for import and export
SN/T 2212 Determination of bensulfuron methyl residues in cereals for import and export - Liquid chromatography SN/T 2228 Determination of 31 acid pesticide residues in foods for import and export - GC-MS method
SN/T 2229 Determination of isoprothiolane residues in foods for import and export SN/T 2233 Determination of fenpropathrin residue in food for import and export
SN/T 2234 Determination of profenofos residue in food for import and export - GC and GC-MS method
SN/T 2320 Determination of chlorthalonil, dichlofluanid, tolylfluanid, captan, folpet, captafol and deltamethrin residues in food for import and export GC-MS method
SN/T 2324 Determination of 33 organophosphrous pesticides residues (butamifos, chlorpyrifos, chlorpyrifos-methyl et al infoodstuffs) for import and export
SN/T 2325 Determination of 45 pesticides residues including azimsulfron, bensulfron-methyl, cinousulfron et al in foods for import and export - HPLC-MS/MS method
SN/T 2397 Method for determination of Nicotine in foods for import and export SN/T 2432 Determination of pyridaben residues in food for import and export
SN/T 2441 Determination of aldicarb,aldicarb-sulfone and aldicarb-sulfoxide residues in food for import and export- LC- MS/MS method
SN/T 2540 Determination of benzoylurea pesticides residues in foodstuffs for import and export- LC-MS/MS method SN/T 2560 Determination of carbamate pesticide residues in food for import and export - LC-MS method
SN/T 2915 Determination of 160 pesticides residues including alachlor,acetochlor,azamethiphos in foodstuffs for export- GC-MS method
SN/T3539 Determination of cyflumetofen in food for export
SN/T3768 Determination of organicphosforus residues in cereal grains for export.GC/MS method SN/T3769 Determination of trichlorfon, phoxim residues in cereal grains for export - LC-MS/MS method SN/T3852: Determination of metaflumizone residues in food for export - LC-MS/MS method
SN/T3859 Determination of butralin pestcide residue in foodstuffs for export
SN/T3860 Determination of pymetrozine residues in food for export.LC-MS/MS method SN/T4264 Determination of metaldehyde residue in foodstuffs for export.GC-MS method SN/T4558 Determination of cyhexatin (azocyclotin) and fenbutatin oxide in foods for export SN/T4586 Determination of thidiazuron residue in foodstuffs for export.GC-MS method YC/T180 Tobacco and tobacco products-Determination of camphechlor residues-GC method
3 Terms and definitions
The terms and definitions below apply to this standard.
3.1 Residue definition
Any particular substance in foods, agricultural products and animal feed due to the use of pesticides, including the pesticide derivatives which is considered to have toxicological significance, such as pesticide conversion products, metabolites, reaction products and impurities, etc.
3.2 Maximum residue limit (MRL)
The statutory maximum concentration of pesticide residues allowed in the internal or surface of foods or agricultural products, expressed as the milligrams of pesticide residues per kilogram of foods or agricultural products (mg/kg).
3.3 Extraneous maximum residue limit (EMRL)
Although some persistent pesticides have been banned, they still could exist in the environment for a long time and therefore cause residues in foods once again; the EMRL in foods are developed in order to control contamination caused by such pesticides in foods. EMRL is expressed as the milligrams of pesticide residues per kilogram of food or agricultural products (mg/kg).
3.4 Acceptable daily intake (ADI)
The estimated amount of a substance, consumed daily for a person’s lifetime, without causing detectable harms to health; expressed by the amount of intake allowed per kilogram of body weight (mg/kg).
4 Technical requirements
4.1 2,4-D and 2,4-D Na
4.1.1 Major purpose of use: herbicide.
4.1.2 ADI: 0.01mg/kgbw.
4.1.3 Residue: 2,4-D.
4.1.4 Maximum residue limit: Shall comply with provisions in the Table 1.
This standard is formulated pursuant to rules provided in the GB/T 1.1 -2009.
This standard replaces the National Food Safety Standard Maximum Residue Limits for Pesticides in Food (GB 2763-2016) and the National Food Safety Standard Maximum Residue Limits for 43 Pesticides in Food (GB 2763.1-2018), and main technical changes are as follows compared with GB 2763-2016 and GB 2763.1-2018:
- Revised the definition of 6 pesticide residues including 2,4-di-isooctyl and the daily allowable intake of 21 pesticides such as Abamectin in the original standard.
- Added 51 kinds of pesticides including 2,4-drip dimethylamine salt, and deleted 1 kind of haloxyfop, and its maximum residue limit is combined into flupiroxicam and haloxyfop-P-methyl;
- Revised the Chinese and English common names of 5 pesticides including metriam.
- Added 2967 maximum pesticide residue limits;
- Revised 28 maximum pesticide residue limits.
- The partial limit values of 12 pesticides including glufosinate-ammonium were changed from temporary limit to formal limit.
- The partial limit values of 17 pesticides such as dithianon were changed from the formal limit to the temporary limit.
- Added 45 testing method standards, removed 17 testing method standards, and revised 9 testing method standards.
- Revised normative annex A, added 22 food names such as lupin, revised 7 food names and revised 2 food classifications;
- Revised normative annex B and added 11 pesticides.
The previous releases of the standards replaced by this standard are as follows:
GB 2763-2005, GB 2763-2012, GB 2763-2014, GB 2763-2016.
GB 2763.1-2018.
1 Scope
National Food Safety Standard Maximum Residue Limits of Pesticides in Foods
This standard sets the 7,107 maximum residue limits of 483 pesticides including 2,4-D, etc. in foods. The standard applies to foods related to residue limits.
The food categories and testing parts (Appendix A) are used to define the application scope of the pesticide’s maximum residue limits, which applies only to this standard. For instance, the maximum residue limit of a pesticide is applicable for a certain food category, all the food in this category will be applicable to this MRL, unless otherwise specified.
The List of Pesticides that are Exempted from Developing MRL Standards in Foods (the Normative Reference Annex B) is used to define the scope of pesticides that do not need MRLs developed in foods.
2 Normative reference
The following documents are essential for the application of this document. For dated references, only the dated versions apply to this standard. For not dated references, the latest versions (including all modifications) apply to this standard.
The supporting testing method that meets the testing requirements is selected for testing. After the release of this standard, the newly released and implemented national food safety standard (GB 23200) is also applicable to the testing of corresponding parameters.
GB/T 5009.19 Determination of organochlorine pesticide multiresidues in foods GB/T 5009.20 Determination of organophosphorous pesticide residues in foods GB/T 5009.21 Determination of carbaryl residues in cereals, oils and vegetables GB/T 5009.36 Analytical methods for hygienic standard of grain
GB/T 5009.102 Determination of phoxim pesticide residues in vegetable foods
GB/T 5009.103 Determination of methamidophos and acephate pesticide residues in vegetable foods GB/T 5009.104 Determination of carbamate pesticide residues in vegetable foods
GB/T 5009.105 Determination of chlorothalonil residues in cucumber GB/T 5009.107 Determination of diazinon residues in vegetable foods
GB/T 5009.110 Determination of cypermethrin,fenvalerate and deltamethrin residues in vegetable foods GB/T 5009.113 Determination of thiocyclam residues in rice
GB/T 5009.114 Determination of bisultap residues in rice GB/T 5009.115 Determination of tricyclazole residues in rice
GB/T 5009.126 Determination of triadmefon residues in vegetable foods GB/T 5009.129 Determination of ethoxyquin residues in fruits
GB/T 5009.130Determination of fomesafen residues in soybeans and cereals GB/T 5009.131 Determination of phosmet residues in vegetable foods
GB/T 5009.132Determination of atrazine residues in foods
GB/T 5009.133 Determination of chlorotoluron residues in grains GB/T 5009.134 Determination of molinate residues in rice
GB/T 5009.135 Determination of chlorbenzuron residues in vegetable foods GB/T 5009.136Determination of quintozene residues in vegetable foods
GB/T 5009.142 Determination of fluazifop-butyl and its acid residues in vegetable food GB/T 5009.143 Determination of amitraz residues in vegetables,fruits,edible oil
GB/T 5009.144 Determination of isofenphos-methyl residues in vegetable foods
GB/T 5009.145 Determination of organophosphorus and carbamate pesticide multiresidues in vegetable foods GB/T 5009.146 Determination of organochlorines and pyrethroid pesticide multiresidues in vegetable foods GB/T 5009.147 Determination of diflubenzuron residues in vegetable foods
GB/T 5009.155 Determination of isoprothiolane residues in rice GB/T 5009.160 Determination of semianitraz residues in fruits
GB/T 5009.161 Determination of organophosphorus pesticide multiresidues in animal foods
GB/T 5009.162 Determination of organochlorine pesticide and pyrethroid pesticide multiresidues in animal original foods
GB/T 5009.164 Determination of butachlor residues in rice
GB/T 5009.165 Determination of 2, 4-D butylate residues in grains
GB/T 5009.172 Determination of trifluralin residues in soybean, peanut, soybean oil, peanut oil. GB/T 5009.174 Determination of metolachlor residues in peanut and soybean
GB/T 5009.175 Determination of 2, 4-D in grains and vegetables
GB/T 5009.176 Determination of dicofol residues in tea, fruits, edible evgetable oils GB/T 5009.177 Determination of propanil residues in rice
GB/T 5009.180 Determination of oxadiazon residues in cereals and peanuts GB/T 5009.184 Determination of buprofezin in cereals and vegetables GB/T 5009.200 Determination of difenzoquat residues in wheat
GB/T 5009.201 Determination of diniconazole residues in pear
GB/T 5009.218 Determination of multi pesticide residues in fruits and vegetables GB/T 5009.219 Determination of the residues of chlorcholine chloride in cereals GB/T 5009.22 0Determination of the residues of anilazine in cereals
GB/T 5009.221 Determination of the residues of diquat in cereals
GB/T 14553 Cereal, Fruit and Vegetable Quality - Determination of Organophosphorus pesticides -Gas chromatography GB/T 14929.2 Method for Determination of Aldicarb Residues in Peanut, Cottonseed Oil and Peanut Oil
GB/T 19650 Method for determination of 478 pesticides and related chemicals residues in animal muscles-GC-MS method GB/T 20769 Determination of 450 pesticides and related chemicals residues in fruits and vegetables-LC-MS-MS method GB/T 20770 Method for determination of 486 pesticides and related chemicals residues in grains-LC-MS-MS method
GB/T 20771 D etermination of 486 pesticides and related chemicals residues in honey - LC-MS-MS method
GB/T 20772 Determination of 461 pesticides and related chemicals residues in animal muscles-LC-MS-MS method GB/T 22243Determination of residue limits of fluroxypyr in rice,vegetable and fruit
GB/T 22979Determination of boscalid residues in milk and milk powder-GC-MS method
GB 23200.2 National Food Safety Standard Testing Methods for Residue of Herbicides Part 2: Determination of Diphenyl Ether Herbicides Residues in Cereal and Oilseed by GC/MS Method
GB 23200.3National Food Safety Standard-Determination of cyclohexanediones herbicide residues in foods Liquid chromatography-mass spectrometry
GB 23200.6National Food Safety Standard Determination of amitrole residue in foods Liquid chromatography-mass spectrometry
GB 23200.8 National Food Safety Standard Determination of Residues of 500 Herbicides and Relevant Chemicals in Fruits and Vegetables by GC/MS Method
GB 23200.9National Food Safety Standard Determination of Residues of 475 Pesticides and Relevant Chemicals in Cereal by GC/MS Method
GB 23200.11National Food Safety Standard Determination of 413 pesticides and related chemicals residues in mulberry twig, honeysuckle, barbary wolfberry fruitand lotus leaf Liqulid chromatography-mass spectrometry
GB 23200.13 National Food Safety Standard Determination of Residues of 448 Pesticides and Relevant Chemicals in Tea Liquid Chromatography-Mass Spectrography
GB 23200.14National Food Safety Standard Determination of Residues of 512 Pesticides and Relevant Chemicals in Fruit/Vegetable Juice and Fruit Wine Liquid Chromatography-Mass Spectrography
GB23200.15 National Food Safety Standard Determination of Residues of 503 Pesticides and Relevant Chemicals in Edible Fungi Gas Chromatography-Mass Spectrography
GB23200.16 National Food Safety Standard Determination of Ethephon Residue in Fruits and Vegetables Gas chromatography
GB23200.19 National Food Safety Standard Determination of Abamectin in Fruits and Vegetables Liquid Chromatography GB23200.20 National Food Safety Standard Determination of Abamectin Residue in Foods Liquid Chromatography-Mass
Spectrography/ Mass Spectrography
GB23200.22 National Food Safety Standard Determination of maleic hydrazide residue in nuts and nut products
GB23200.24 National Food Safety Standard Determination of Eleven Herbicides Residues in Grains and Soybean Gas Chromatography-Mass Spectrography
GB23200.29 National Food Safety Standard Determination of Fenpyroximate Residue in Fruits and Vegetables Liquid Chromatography
GB23200.31 National Food Safety Standard Determination of flumioxazin Residue in Foods Gas Chromatography-Mass Spectrography
GB23200.32 National Food Safety Standard Determination of Daminozide Residue in Foods Gas Chromatography-Mass Spectrography
GB23200.33 National Food Safety Standard–Determination of Benoxacor, Anilofos,Allidochlor 110 pesticides residues in foods Gas chromatography-mass spectrometry
GB23200.34 National Food Safety Standard Determination of 65 Pesticides in Foods (including Aldoxycarb, Pyraclostrobine and Azoxystrobin) Liquid Chromatography–Mass Spectrometry / Mass Spectrometry
GB23200.37 National Food Safety Standard Determination of 20 Pesticides Residues in Foods (including Nitenpyram, Dinotefuran) Liquid Chromatography–Mass Spectrometry / Mass Spectrometry
GB23200.38 National Food Safety Standard-Determination of cyclohexanedione herbicides residue in plant-derived foods Liquid chromatography-mass spectrometry
GB23200.39 National Food Safety Standard-Determination of thiamethoxam and its metabolite clothianidin residues in foods Liquid chromatography-mass spectrometry
GB23200.43 National Food Safety Standard Determination of Quinclorac Residue in Grains and Oil Seeds Gas chromatography
GB23200.45 National Food Safety Standard-Determination of diflubenzuron residue in foods-Liquid chromatography-mass spectrometry
GB23200.46 National Food Safety Standard-Determination of Pyrimethanil, Mepanipyrim, Myclobutanil, Azoxystrobin Resides in Foods Gas Chromatography-Mass Spectrography
GB23200.47 National Food Safety Standard Determination of Clofentezine Residue in Foods Gas Chromatography-Mass Spectrography
GB23200.49 National Food Safety Standard Determination of Difenoconazole Residue in Foods Gas Chromatography-Mass Spectrography
GB23200.50 National Food Safety Standard Determination of pyridine pesticides residue in foods Liquid chromatography - mass spectrometry
GB23200.51 National Food Safety Standard Determination of Dinotefuran Residue in Foods Liquid Chromatography–Mass Spectrometry / Mass Spectrometry
GB23200.53 National Food Safety Standard Determination of flusilazole Residue in Foods Gas Chromatography-Mass Spectrography
GB23200.54 National Food Safety Standard Determination of Strobilurin Fungicide Residues in Foods Gas Chromatography-Mass Spectrography
GB23200.56 National Food Safety Standard-Determination of quinoxyfen residue in foods GB23200.57 National Food Safety Standard Determination of acetochlor Residue in Foods GB23200.60 National Food Safety Standard Determination of Clodinafop-propargyl Residue in Foods
GB23200.62 National Food Safety Standard–Determination of flumiclorac-pentyl residue in foods-Gas chromatography- mass spectrometry
GB23200.64 National Food Safety Standard-Determination of pyriproxyfen residue in foods-Liquid chromatography-mass spectromtry
GB23200.65 National Food Safety Standard Determination of tetraconazole residues in food
GB23200.68 National Food Safety Standard–determination of boscalid residue in foods Gas chromatography-mass spectrometry
GB23200.69 National Food Safety Standard Determination of dinitroaniline Pesticide Residue in Foods Liquid Chromatography–Mass Spectrometry / Mass Spectrometry
GB23200.70 National Food Safety Standard Determination of Acifluorfen Residue in Foods Liquid Chromatography–Mass Spectrometry / Mass Spectrometry
GB23200.72 National Food Safety Standard-Determination of phenylbenzamide pesticides residues in foods Gas chromatography-mass spectrometry
GB23200.73 National Food Safety Standard-Determination of rotenone and azadirachtin residues in foods-Liquid Chromatography-mass spectrometry
GB23200.74 National Food Safety Standard Determination of Jiangangmycin Residue in Foods Liquid Chromatography– Mass Spectrometry / Mass Spectrometry
GB23200.75 National Food Safety Standard–Determination of flonicamid residue in foods
GB23200.76 National Food Safety Standard-Determination of flubendiamide residue in foods Liquid chromatography-mass spectrometry
GB23200.83 National Food Safety Standard Testing Methods of Iprobenfos Residue in Foods
GB23200.104 National Food Safety Standard–Determination of MCPA and MCPB residues in meat and meat products Liquid chromatography-mass spectrometry
GB23200.108 National Food Safety Standard-Determination of glufosinate-ammonium residue in foods of plant origin- Liquid chromatography tandem mass spectrometry
GB23200.109 National Food Safety Standard-Determination of clopyralid in foods of plant origin- Liquid chromatography- mass spectrometry
GB23200.110 National Food Safety Standard-Determination of forchlorfenuron in foods of plant origin-Liquid chromatography tandem mass spectrometry
GB23200.111 National Food Safety Standard-Determination of flumetsulamin foods of plant origin-Liquid chromatography tandem mass spectrometry
GB23200.112 National Food Safety Standard–Determination of 9 carbamate pesticides and metabolites residues in foods of plant origin-Liquid chromatography-post-column derivation method
GB23200.113 National Food Safety Standard Determination of 208 pesticides and metabolites residues in foods of plant origin- Gas chromatography-tandem mass spectrometry method
GB23200.115 National Food Safety StandardDetermination of fipronil and metabolites residues in eggs Liqiud chromatography-tandem mass spectrometry method
GB/T23204 Determination of 519 pesticides and related chemicals residues in tea. GC-MS method GB/T23210 rmination of 511 pesticides and related chemicals residues in milk and milk powder -GC-MS
GB/T23211 Determination of 493 pesticides and related chemicals residues in milk and milk powder –LC-MS-MS method GB/T23376 Determination of pesticides residues in tea - GC/MS method
GB/T23379 Determination of imidacloprid residues in fruits,vegetables and teas - HPLCHPLC
GB/T23584 Determination of acetamiprid residue in fruits and vegetables – Liquid chromatography-tandem mass spectrometry
GB/T23750 Determination of Glyphosate residues in plant products-GC-MS method GB/T23816 Method for determination of triazine herbicide residues in soybean GB/T23818 Determination of imidazolinone herbicide residues in soybean
GB/T25222 Inspection of grain and oils - Determination of phosphide residues in grain - Spectrophotometric method GB29707 National Food Safety StandardDetermination of marker residues of Amitraz in milk by Gas Chromatographic
method
NY/T 761 Pesticide multi-residue screen methods for determination of organophosphorus pesticides, organochlorine pesticides, pyrethroid pesticides and carbamate pesticides in vegetables and fruits
NY/T1096 Determination of Glyphosate Residues in food
NY/T1277 Determination of Iprodione Residues in Vegetables by HPLC
NY/T1379 Multi-residue Determination of 334 Pesticides in Vegetable by GC/MS and LC/MS NY/T1434 Multi-residue Determination of 2 4 - D and Other 12 Herbicides in Vegetable by LC/MS NY/T1453 Determination of 16 pesticide residues in fruits and vegetables by LC - MS/MS NY/T1455 Determination of myclobutanil residue in fruits by gas chromatogram
NY/T1456 Determination of prochloraz residue in fruits by gas chromatography
NY/T1616 Determination of Nine sulfonylurea herbicides residues in soils by LC-MS NY/T1652 Determination of propargite residues in vegetables and fruits - GC
NY/T1679 Determination of carbamate pesticide residues in vegetable foods by LC - MS/MS
NY/T1680 Determination of Carbendazim and other Three Benzimidazoles in vegetable and fruit by HPLC NY/T1720 Determination of seven benzoylurea pesticides residues in fruits and vegetables by HPLC NY/T1722 Determination of anilazine residue in vegetables by HPLC
NY/T1725 Determination of cyromazine residue in vegetables by HPLC
NY/T2820 Determination of yishijing tebufenozide, methoxyfenozide, furan tebufeno zide and chromafenozide residues in plant foods-LC-MS-MS method
SN/T0134 Determination of pesticide residues of 12 kinds carbamates including oxamyl in foods for import and export –LC- MS/MS method
SN/T0139 Method for determination of dithiocarbamate residues in grain for export SN/T0157 Method for determination of dithiocarbamateresidue in fruit for export
SN/T0162 Method for the determination of thiophanate-methyl, thiophanate, carbendazim, benomyl and thiabendazole residues in foods for exports - HPLCHPLC
SN/T0192 Method for determination of bromopropylate residues in fruits for export
SN/T0217 Determination of Residual Amounts of Various Chrysanthemum Esters in Plant-derived Foods for Export-Gas Chromatography-Mass Spectrometry
SN/T0293 Determination of Paraquat and diquat Residues in Plant-derived Foods for Export-Liquid Chromatography-Mass Spectrometry/Mass Spectrometry
SN/T0519 Determination of propiconazole residue in food for import and export SN/T0525 Determination of phenylbutatin residues in cereals and oilseeds for export
SN/T0592 Method for the determination of fenbutatin oxide residues in cereals and oil seeds for export SN0654 Method for the determination of captan residues in fruits for export
SN/T0685 Method for the determination of propamocarb residues inf cereals for export SN/T0695 Method for the determination of triforine residues in cereals for export SN/T0697 Determination of oxamyl residues in export meat and meat products SN/T0701 Method for the determination of phosphamidon residues in cereals for export
SN/T0931 Method for the determination of prohexadione-calcium residue in cereals for exports - Liquid chromatography SN/T 1477 Inspection of paclobutrazol residues in food for import and export
SN/T 1541 Inspection of the total residues of dithiocarbamate pesticides in tea for export
SN/T 1605 Inspection of cyanazin fluometuron atrazine propanil and linuron residues in products of plant origin for import and export - HPLC
SN/T 1606 Inspection of phenoxy acid herbicides residues in products of plant origin for import and export - gc
SN/T 1739 Determination of organophosphrous pesticides residues in cereals and oil seeds for import and export-Gas chromatography mass spectrometry method
SN/T 1923 Determination of glyphosate residues in food for import and export - HPLC-MS/MS method SN/T 1968 Determination of prometryne residues in food for import and export.GC-MS Method
SN/T 1969 Determination of bifenthrin residue in food for import and export-GC-MS method
SN/T 1976 Determination of azoxystrobin residues in fruit and vegetable for import and export-GC method SN/T 1982 Determination of fipronil residues in food for import and export-GC-MS method
SN/T 1986 Determination of chlorfenapyr residues in food for import and export
SN/T 2095 Determination of chlorfluazuron residues in vegetables for import and export - HPLC SN/T 2147 Determination of cadusafos residues in food for import and export
SN/T 2151 Determination of pesticides residue of 28 kinds of including bioresmethrin, acinathrin, bifenthrin in food import and export - GC-MS method
SN/T 2152 Determination of hexaflumuron residue in food for import and export - HPLC-MS/MS method SN/T 2158 Determination of chlorpyrifos residue in foods for import and export
SN/T 2212 Determination of bensulfuron methyl residues in cereals for import and export - Liquid chromatography SN/T 2228 Determination of 31 acid pesticide residues in foods for import and export - GC-MS method
SN/T 2229 Determination of isoprothiolane residues in foods for import and export SN/T 2233 Determination of fenpropathrin residue in food for import and export
SN/T 2234 Determination of profenofos residue in food for import and export - GC and GC-MS method
SN/T 2320 Determination of chlorthalonil, dichlofluanid, tolylfluanid, captan, folpet, captafol and deltamethrin residues in food for import and export GC-MS method
SN/T 2324 Determination of 33 organophosphrous pesticides residues (butamifos, chlorpyrifos, chlorpyrifos-methyl et al infoodstuffs) for import and export
SN/T 2325 Determination of 45 pesticides residues including azimsulfron, bensulfron-methyl, cinousulfron et al in foods for import and export - HPLC-MS/MS method
SN/T 2397 Method for determination of Nicotine in foods for import and export SN/T 2432 Determination of pyridaben residues in food for import and export
SN/T 2441 Determination of aldicarb,aldicarb-sulfone and aldicarb-sulfoxide residues in food for import and export- LC- MS/MS method
SN/T 2540 Determination of benzoylurea pesticides residues in foodstuffs for import and export- LC-MS/MS method SN/T 2560 Determination of carbamate pesticide residues in food for import and export - LC-MS method
SN/T 2915 Determination of 160 pesticides residues including alachlor,acetochlor,azamethiphos in foodstuffs for export- GC-MS method
SN/T3539 Determination of cyflumetofen in food for export
SN/T3768 Determination of organicphosforus residues in cereal grains for export.GC/MS method SN/T3769 Determination of trichlorfon, phoxim residues in cereal grains for export - LC-MS/MS method SN/T3852: Determination of metaflumizone residues in food for export - LC-MS/MS method
SN/T3859 Determination of butralin pestcide residue in foodstuffs for export
SN/T3860 Determination of pymetrozine residues in food for export.LC-MS/MS method SN/T4264 Determination of metaldehyde residue in foodstuffs for export.GC-MS method SN/T4558 Determination of cyhexatin (azocyclotin) and fenbutatin oxide in foods for export SN/T4586 Determination of thidiazuron residue in foodstuffs for export.GC-MS method YC/T180 Tobacco and tobacco products-Determination of camphechlor residues-GC method
3 Terms and definitions
The terms and definitions below apply to this standard.
3.1 Residue definition
Any particular substance in foods, agricultural products and animal feed due to the use of pesticides, including the pesticide derivatives which is considered to have toxicological significance, such as pesticide conversion products, metabolites, reaction products and impurities, etc.
3.2 Maximum residue limit (MRL)
The statutory maximum concentration of pesticide residues allowed in the internal or surface of foods or agricultural products, expressed as the milligrams of pesticide residues per kilogram of foods or agricultural products (mg/kg).
3.3 Extraneous maximum residue limit (EMRL)
Although some persistent pesticides have been banned, they still could exist in the environment for a long time and therefore cause residues in foods once again; the EMRL in foods are developed in order to control contamination caused by such pesticides in foods. EMRL is expressed as the milligrams of pesticide residues per kilogram of food or agricultural products (mg/kg).
3.4 Acceptable daily intake (ADI)
The estimated amount of a substance, consumed daily for a person’s lifetime, without causing detectable harms to health; expressed by the amount of intake allowed per kilogram of body weight (mg/kg).
4 Technical requirements
4.1 2,4-D and 2,4-D Na
4.1.1 Major purpose of use: herbicide.
4.1.2 ADI: 0.01mg/kgbw.
4.1.3 Residue: 2,4-D.
4.1.4 Maximum residue limit: Shall comply with provisions in the Table 1.